From the Database Management, select Add Mailbox Database copy.

Select a target mailbox server

Adding..


Added

Verify the completion

On EXB2, mailbox copy has started.

Do the same for the EXB2/DB2

Isn't this easy?
Wow finally! A space I can post all about my experience with exchange and clustering.
1. Install "Network Load Balancing" feature on each CAS+HT servers.
2. Setup the NLB (in my case my nlb name is "webmail.demo.local"), exf1 and exf2 are the members, also add it to DNS.
3. set a new client access array using new-ClientAccessArray command, it will be used among outlook clients (MAPI) to connect to the exchagne 2010 servers.
There are a few possible installation issues that we would like you to be aware of:
1. Exchange 2007 managed services might time out during certificate revocation checks
2. When installing a Rollup, we recommend you use the same account that you used to install Exchange Server. If you are using a different account, that account needs to have Local Administrator rights as well as rights to read Active Directory on Exchange object as well as server level (as the update needs to determine which roles are installed on the server). Not having required permissions can lead to OWA not being updated correctly and displaying a blank page after update has completed.
3. If you have modified the logon.aspx file, it will not be patched by the Update Rollup installer. As a result Outlook Web Access may not be updated correctly and it may display a blank page after the update has finished. In order to avoid this problem, rename the logon.aspx file before applying the update rollup. After you apply an update rollup package, you must re-create Outlook Web Access customization in logon.aspx.
Before I post detailed steps, here is a migration plan.
The 2x E2K3 OWA (NLB) and 2x E2K3 clustered backend servers will be replaced/migrated to